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Strained ring systems. VI. A facile rearrangement of endo-bicyclo[2.2.O]hex-2-yl acetate

✍ Scribed by Richard N. McDonald; Gerald E. Davis

Book ID: 108385223
Publisher: Elsevier Science
Year: 1968
Tongue: French
Weight: 132 KB
Volume: 9
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)98976-2

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Of the several methods now available for preparing derivatives of bicyclo[2.2.O]hexane, the Scherer synthesis 2,3 offers certain practical advantages. The key step in the synthetic sequence is the semi-benzilic acid ring contraction of 1,4-dichlorobicyclo[2.2.l]heptan-7one (&) with powdered sodium h