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Strain-promoted 1,3-dipolar cycloadditions of diazo compounds with cyclooctynes

✍ Scribed by Moran, Joseph; McKay, Craig S.; Pezacki, John Paul


Book ID
118020385
Publisher
NRC Research Press
Year
2011
Tongue
French
Weight
397 KB
Volume
89
Category
Article
ISSN
0008-4042

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πŸ“œ SIMILAR VOLUMES


ChemInform Abstract: Strain-Promoted 1,3
✍ Joseph Moran; Craig S. McKay; John Paul Pezacki πŸ“‚ Article πŸ“… 2011 πŸ› John Wiley and Sons βš– 25 KB

## Abstract Reactions of cyclooctyne with diazoalkanes (IVa) and (VI) containing electron‐donating groups proceed with very high reaction rates which are comparable to those obtained in analogous cycloaddition reactions employing azides or nitrones.

1,3-Dipolar cycloaddition reactions of c
✍ Kiyoshi Matsumoto; Ryuji Ohta; Takane Uchida; Hiroyasu Nishioka; Maki Yoshida; A πŸ“‚ Article πŸ“… 1997 πŸ› Journal of Heterocyclic Chemistry 🌐 English βš– 387 KB

## Abstract Cyclooctyne smoothly underwent 1,3‐dipolar cycloaddition with pyridinium dicyanomethylides to afford the corresponding indolizines (8‐cyario‐7‐azatricyclo[7.6.0.0^2,7^]pentadeca‐1,3,5,8‐tetraenes) in excellent yields.