Strain in 1, 3-dimethylbicyclo[1.1.0]butane
β Scribed by Richard B. Turner; Peter Goebel; W. von E. Doering; J.F. Coburn Jr.
- Publisher
- Elsevier Science
- Year
- 1965
- Tongue
- French
- Weight
- 271 KB
- Volume
- 6
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
2. Addition of Lip-thiocresolate gives a mixture of ( l ) , (Ia), ( l b ) , ( l c ) , i.e. p-tolylthio groups are incorporated into the carbenoid via (2) ; after a reaction time of 20 h at a temperature of -lOΒ°C the mixture was hydrolysed with D2O and H20 and the formation of the lithium compounds (
The thermal isomerization of the title compounds was studied in the vapor phase. Over the temperature range from 445.1 to 477.5"K7 1,4-dimethylbicyclo[2.2.O]hexane underwent a homogeneous unimolecular reaction to 2,5-dimethyl-175-hexadiene, the rate constants being represented by the equation: k =