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Strain in 1, 3-dimethylbicyclo[1.1.0]butane

✍ Scribed by Richard B. Turner; Peter Goebel; W. von E. Doering; J.F. Coburn Jr.


Publisher
Elsevier Science
Year
1965
Tongue
French
Weight
271 KB
Volume
6
Category
Article
ISSN
0040-4039

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πŸ“œ SIMILAR VOLUMES


1, 3-dimethylbicyclo[1.1.0]butane
✍ W. von E. Doering; J.F. Coburn Jr. πŸ“‚ Article πŸ“… 1965 πŸ› Elsevier Science 🌐 French βš– 216 KB
Synthesis of 1,3-Dimethylbicyclo[1.1.0]b
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2. Addition of Lip-thiocresolate gives a mixture of ( l ) , (Ia), ( l b ) , ( l c ) , i.e. p-tolylthio groups are incorporated into the carbenoid via (2) ; after a reaction time of 20 h at a temperature of -lOΒ°C the mixture was hydrolysed with D2O and H20 and the formation of the lithium compounds (

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The thermal isomerization of the title compounds was studied in the vapor phase. Over the temperature range from 445.1 to 477.5"K7 1,4-dimethylbicyclo[2.2.O]hexane underwent a homogeneous unimolecular reaction to 2,5-dimethyl-175-hexadiene, the rate constants being represented by the equation: k =

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