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Straightforward Synthesis of Perhydrofuro[2,3-b]furans through a Wacker-Type Reaction

✍ Scribed by Francisco Alonso; Daniel Sánchez; Tatiana Soler; Miguel Yus


Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
353 KB
Volume
350
Category
Article
ISSN
1615-4150

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The dimeric gallium-phosphorus compound [(Me 3 Si-CH 2 ) 2 GaP(SiMe 3 ) 2 ] 2 (1) was prepared from the 1:1 mole ratio lithium-halide elimination reaction of (Me 3 SiCH 2 ) 2 GaP(SiMe 3 ) 2 Ga(CH 2 SiMe 3 ) 2 Cl with LiP-(SiMe 3 ) 2 in benzene solution and has been characterized through multinuclear