Straightforward selective synthesis of linear 1-O-alkyl glycerol and di-glycerol monoethers
✍ Scribed by Yan Shi; Wissam Dayoub; Alain Favre-Réguillon; Guo-Rong Chen; Marc Lemaire
- Book ID
- 104097009
- Publisher
- Elsevier Science
- Year
- 2009
- Tongue
- French
- Weight
- 511 KB
- Volume
- 50
- Category
- Article
- ISSN
- 0040-4039
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📜 SIMILAR VOLUMES
A novel series of synthetic glycolipids, i,3-di-O-alkyl-2-O-(/3-glycosyl)glycerols, and their efficient synthetic route were proposed. These glyceroglycolipids were synthesized in good overall yields and stereoselectivity in five steps via trichloroacetimidate glycosylation with 1,3-di-O-alkylglycer
R(-)-2,3-and S(+)-1,2-O-Isopropylidene-sn-glycerols (4 and 9) are converted into 2-Oarachidonoyl-1-O-stearoyl and2-O-arachidonoyl-3-O-stearoyl-sn-glycerols (2 and3, respectively); glycerol is also converted into its racemic 1,2-and its symmetrical 1,3-di-O-linoleoylderivatives (14 and 17, respective