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Storage characteristics of cathodes for Li-ion batteries

✍ Scribed by G. Pistoia; A. Antonini; R. Rosati; D. Zane


Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
590 KB
Volume
41
Category
Article
ISSN
0013-4686

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✦ Synopsis


Ahatraet-The storage characteristics of LiMn,O,, LiCoO, and LiNiO, have been evaluated in liquid electrolytes commonly used in lithium-ion batteries. All materials show self-discharge phenomena even at moderate oxidation levels. Three mechanisms are thought to be operating in this process: (a) electrolyte decomposition ; (b) spontaneous Li + reinsertion due to instability of the delithiated cathodes; (c) solu- bility by corrosion. Mechanisms (a) and (c) have been much in evidence in the impedance tests.


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