Stopped-Flow Kinetics Investigation of the Imidazole-Catalyzed Peroxyoxalate Chemiluminescence Reaction
β Scribed by Hadd, Andrew G.; Robinson, Alex L.; Rowlen, Kathy L.; Birks, John W.
- Book ID
- 126892916
- Publisher
- American Chemical Society
- Year
- 1998
- Tongue
- English
- Weight
- 110 KB
- Volume
- 63
- Category
- Article
- ISSN
- 0022-3263
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
The peroxyoxalate system undergoes one of the most efficient chemiluminescence reactions and is the only one considered to involve an intermolecular chemically initiated electron exchange luminescence mechanism, with proven high efficiency. Several reactive intermediates have been proposed, which, u
## Abstract Kinetics of the reaction of CO2 and ethylethanolamine (EMEA) in aqueous solutions has been studied using the stopped-flow technique with conductivity detection. Measurements were performed at 288 K, 293 K, 298 K, and 303 K. Amine concentration ranged from 10 mol mβ3 to 37.5 mol mβ3. The