Stopped-flow kinetic determination of acetaminophen by oxidation with a 1,10-phenanthroline/iron(III)complex
✍ Scribed by M. Carmona; M. Silva; D. Pérez-Bendito
- Book ID
- 108304005
- Publisher
- Elsevier Science
- Year
- 1989
- Tongue
- English
- Weight
- 697 KB
- Volume
- 218
- Category
- Article
- ISSN
- 0003-2670
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Dicyanobis(l,lO-phenanthroline)iron(II)-modified glassy carbon electrodes were shown to exhibit an electrocatalytic response for the oxidation of acetaminophen with a decrease of 100 mV in the potential required. It can also inhibit the oxidation of ascorbic acid and uric acid. When used for amperom
Iron(III)-1 ,10-phenanthroline complex obtained, in situ, by direct mixing of iron(II1) and 1 , 1 0-phenantbroline, oxidizes V(N). The reaction is markedly accelerated by sodium dodecyl sulphate. The rate-[surfactant] profile exhibits a maximum. The kinetic analysis of the micellar effect has been
## Abstract The kinetics of oxidation of several substituted quinols by a series of Tris(1,10‐phenanthroline)iron(III) complexes has been investigated with a stopped‐flow technique at 6.0 and 20.0°C. The reactions were found to be first order on both reactants and independent of acidity. The second