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Stoichiometry and kinetics of the reduction of C4(OH2)5Ch2I2+ by chromium(II)

✍ Scribed by Nohr, Ronald S.; Spreer, Larry O.


Book ID
120088756
Publisher
American Chemical Society
Year
1974
Tongue
English
Weight
626 KB
Volume
13
Category
Article
ISSN
0020-1669

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Kinetic studies of the reactions CH2I2 +
✍ Shozo Furuyama; David M. Golden; Sidney W. Benson πŸ“‚ Article πŸ“… 1969 πŸ› John Wiley and Sons 🌐 English βš– 489 KB πŸ‘ 1 views

The rate of the reaction CH212 + H I 2 CH,I + I , has been followed spectrophotometrically from 201 .O to 31 1 .Z0. The rate constant for the reaction I + CH,I, CH,I + I, fits the equation, log (k,/M-'sec-') = 11.45 f 0.18 -(15.11 f 0.44)/0. This value, combined with the assumption that E2 = 0 & 1 k