Stoichiometry and kinetics of the ceric(IV) oxidation of hydrazine in acid media
β Scribed by Morrow, Jack I.; Sheeres, Gary W.
- Book ID
- 127141235
- Publisher
- American Chemical Society
- Year
- 1972
- Tongue
- English
- Weight
- 363 KB
- Volume
- 11
- Category
- Article
- ISSN
- 0020-1669
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π SIMILAR VOLUMES
The rates of oxidation of four a-keto acids, glyoxylic, pyruvic, phenylglyoxylic, and 2oxobutyric acids by Cerium(1V) in H2S04-HaHS04 and HzS04-HC104 solutions, have been studied spectrophotometrically. The rate data suggest that CeSO:' is the most reactive of the Cerium(1V)-sulfate complexes presen
The title Mn IV complex, [Mn(LH 2 ) 3 ] 4 (LH 2 biguanide H 2 NC( NH)NHC( NH)NH 2 ), an authentic two-electron oxidant, quantitatively oxidizes hydrazine (H 2 NNH 2 ) to dinitrogen in the pH interval 2.00 Β± 3.50. The net four-electron oxidation of hydrazine is provided by two Mn IV as established by