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Stoichiometric reactions of Tπ-allyl complexes of palladium with organotin compounds and the nature of the palladium intermediate in catalytic reactions of RSnMe3WITH CH2=CHCH2X

✍ Scribed by N. A. Bumagin; A. N. Kasatkin; I. P. Beletskaya


Book ID
112444773
Publisher
Springer
Year
1983
Tongue
English
Weight
518 KB
Volume
32
Category
Article
ISSN
1573-9171

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Treatment of tetrakis(tripheny1phosphine)platinum with elemental selenium (red or vitreous) in toluene solution under reflux yields an insoluble solid. This dissolves in dichloromethane with reaction, eventually to form a I : I mixture of [PtCl,(PPh,)J and the new compound [Pt(Se,CH,) (PPh,)J, which