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Palladium(0)-Catalyzed Allylic Aminations: Kinetics and Mechanism of the Reaction of Secondary Amines with Cationic [( η 3 -allyl)PdL 2 ] + Complexes †

✍ Scribed by Amatore, Christian; Génin, Emilie; Jutand, Anny; Mensah, Laure


Book ID
126131462
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
134 KB
Volume
26
Category
Article
ISSN
0276-7333

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✍ Christian Amatore; Sophie Gamez; Anny Jutand 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 155 KB 👁 1 views

The oxidative addition of the allylic acetate, CH 2 CH À CH 2 À OAc, to the palladium(0) complex [Pd 0 (P,P)], generated from the reaction of [Pd(dba) 2 ] with one equivalent of P,P (P,P dppb 1,4-bis(diphenylphosphanyl)butane, and P,P dppf 1,1'-bis(diphenylphosphanyl)ferrocene), gives a cationic (h