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Rate and mechanism of the reversible formation of a cationic (η3-allyl)palladium(II) complex in the oxidative addition of allylic acetate to a palladium(0) complex ligated by diop: an unusual behavior

✍ Scribed by Christian Amatore; Sophie Gamez; Anny Jutand


Book ID
108346834
Publisher
Elsevier Science
Year
2001
Tongue
English
Weight
126 KB
Volume
624
Category
Article
ISSN
0022-328X

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Rate and Mechanism of the Reversible For
✍ Christian Amatore; Sophie Gamez; Anny Jutand 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 155 KB 👁 1 views

The oxidative addition of the allylic acetate, CH 2 CH À CH 2 À OAc, to the palladium(0) complex [Pd 0 (P,P)], generated from the reaction of [Pd(dba) 2 ] with one equivalent of P,P (P,P dppb 1,4-bis(diphenylphosphanyl)butane, and P,P dppf 1,1'-bis(diphenylphosphanyl)ferrocene), gives a cationic (h