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Reversible Formation of a Cationic Palladium(II) Hydride [HPd(PPh3)2]+ in the Oxidative Addition of Acetic or Formic Acid to Palladium(0) in DMF

โœ Scribed by Christian Amatore; Anny Jutand; Gilbert Meyer; Italo Carelli; Isabella Chiarotto


Publisher
John Wiley and Sons
Year
2000
Tongue
English
Weight
307 KB
Volume
2000
Category
Article
ISSN
1434-1948

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Rate and Mechanism of the Reversible For
โœ Christian Amatore; Sophie Gamez; Anny Jutand ๐Ÿ“‚ Article ๐Ÿ“… 2001 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 155 KB

The oxidative addition of the allylic acetate, CH 2 CH ร€ CH 2 ร€ OAc, to the palladium(0) complex [Pd 0 (P,P)], generated from the reaction of [Pd(dba) 2 ] with one equivalent of P,P (P,P dppb 1,4-bis(diphenylphosphanyl)butane, and P,P dppf 1,1'-bis(diphenylphosphanyl)ferrocene), gives a cationic (h