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Sterol metabolism. XXIV. Unlikely participation of singlet molecular oxygen in several enzyme oxygenations

✍ Scribed by Teng, Jon I.; Smith, Leland L.

Book ID
126246340
Publisher
American Chemical Society
Year
1973
Tongue
English
Weight
293 KB
Volume
95
Category
Article
ISSN
0002-7863

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πŸ“œ SIMILAR VOLUMES

Sterol metabolism. XLIII. The oxidation
Sterol metabolism. XLIII. The oxidation of cholest-4-en-3Ξ²-ol by singlet molecular oxygen
✍ Jon I. Teng; Chow-Eng Low; Leland L. Smith πŸ“‚ Article πŸ“… 1978 πŸ› Elsevier Science 🌐 English βš– 498 KB

The photosemitized oxidation of cholest-4-en-3#-ol in which singlet molecular oxygen is implicated yielded eholut4-en-3-one and the isomeric epoxides 4~,5-epoxy-5~-cholestan-3-one and 4#,5-epoxy-50-cholestan-3-one, the epoxides being formed in the ratio 3 : 1. Oxidation of cholest4~n-3-one by alkali