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STEROL METABOLISM. XLII. ON THE INTERCEPTION OF SINGLET MOLECULAR OXYGEN BY STEROLS

✍ Scribed by Leland L. Smith; Jonathan P. Stroud


Book ID
114892674
Publisher
John Wiley and Sons
Year
1978
Tongue
English
Weight
547 KB
Volume
28
Category
Article
ISSN
0031-8655

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Sterol metabolism. XLIII. The oxidation
✍ Jon I. Teng; Chow-Eng Low; Leland L. Smith πŸ“‚ Article πŸ“… 1978 πŸ› Elsevier Science 🌐 English βš– 498 KB

The photosemitized oxidation of cholest-4-en-3#-ol in which singlet molecular oxygen is implicated yielded eholut4-en-3-one and the isomeric epoxides 4~,5-epoxy-5~-cholestan-3-one and 4#,5-epoxy-50-cholestan-3-one, the epoxides being formed in the ratio 3 : 1. Oxidation of cholest4~n-3-one by alkali