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Steroids. LXXIX. Synthesis and reactions of oxiranes obtained from 3- and 16-oxo steroids

✍ Scribed by Cook, C. E.; Corley, Robert C.; Wall, Monroe E.


Book ID
115514714
Publisher
American Chemical Society
Year
1968
Tongue
English
Weight
730 KB
Volume
33
Category
Article
ISSN
0022-3263

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Synthesis of Ξ”4-3-oxo-steroids labelled
✍ P. Toft; A. J. Liston; A. Y. Viau πŸ“‚ Article πŸ“… 1973 πŸ› John Wiley and Sons 🌐 French βš– 159 KB

## Abstract [6β‐^2^H] Testosterone and [6β‐^3^H] Testosterone were each synthesized in good yield in three steps: Treatment of 5a, 6a‐ epoxy‐3, 3‐ethylene‐dioxyandrostan ‐17β‐ol with labelled lithium aluminum hydride is followed by deacetalation and dehydration under carefully controlled basic cond