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Steroids. 2. Synthesis of C-18 functionalized steroids via the Smith-Hughes route

โœ Scribed by Pillai, K. M. R.; Murray, W. V.; Shooshani, I.; Williams, D. L.; Gordon, D.; Wang, S. Y.; Johnson, Francis

Book ID
126951165
Publisher
American Chemical Society
Year
1984
Tongue
English
Weight
1022 KB
Volume
27
Category
Article
ISSN
0022-2623

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๐Ÿ“œ SIMILAR VOLUMES

Steroids I. Alkylation of ฮฒ-ketoesters v
Steroids I. Alkylation of ฮฒ-ketoesters via their Cu(II) enolates in aqueous media. Application of the synthesis of C-18 functionalized steroids via the torgov approach.
โœ Plato A. Magriotis; William V. Murray; Francis Johnson ๐Ÿ“‚ Article ๐Ÿ“… 1982 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 216 KB

Three steroidal pentaenes ( a-r;) have been synthesized, the key step being the 81 alkylatlon of the Cu(I1) the ates of the ring D precursors ($22) by the isothiouronium acetate J, in aqueous solution.