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Steroidal adducts. III. Novel dehydrogenations of steroids via ene adducts with tetracyanoethylene

โœ Scribed by Andrews, Anne L.; Fort, Raymond C.; Le Quesne, P. W.

Book ID
126781551
Publisher
American Chemical Society
Year
1971
Tongue
English
Weight
675 KB
Volume
36
Category
Article
ISSN
0022-3263

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Novel ene- reactions of tetracyanoethyle
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โœ Anne M. Lautzenheiser; P.W. LeQuesne ๐Ÿ“‚ Article ๐Ÿ“… 1969 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 193 KB

Recently-described work1 on the ene-reaction between acrylonitrile and ergosteryl acetate to give the adducts (I-III) leads us to report our investigation of some unusual reactions of tetracyanoethylene with three steroidal cisoid dienes. Tetracysnoethylene reacted rapidly with ergosteryl acetate in