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Sterically Hindered Benzophenones via Rhodium-Catalyzed Oxidative Arylation of Aldehydes

✍ Scribed by Chuzel, Olivier; Roesch, Alexander; Genet, Jean-Pierre; Darses, Sylvain


Book ID
127071251
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
149 KB
Volume
73
Category
Article
ISSN
0022-3263

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Grignard-Type Arylation of Aldehydes via
✍ Luo Yang; Camille A. Correia; Chao-Jun Li πŸ“‚ Article πŸ“… 2011 πŸ› John Wiley and Sons 🌐 English βš– 188 KB

An efficient Grignard-type arylation of aldehydes via aryl C Γ€ H activation was achieved under mild conditions catalyzed by rhodium. The reaction provides an easy access to a wide variety of benzyl alcohols and can tolerate various functional groups as well as air and water.