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Grignard-Type Arylation of Aldehydes via a Rhodium-Catalyzed CH Activation under Mild Conditions

✍ Scribed by Luo Yang; Camille A. Correia; Chao-Jun Li

Publisher: John Wiley and Sons
Year: 2011
Tongue: English
Weight: 188 KB
Volume: 353
Category: Article
ISSN: 1615-4150
DOI: 10.1002/adsc.201100232

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✦ Synopsis

An efficient Grignard-type arylation of aldehydes via aryl C À H activation was achieved under mild conditions catalyzed by rhodium. The reaction provides an easy access to a wide variety of benzyl alcohols and can tolerate various functional groups as well as air and water.

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