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Sterically-Controlled Regioselective para-Substitutions of Aniline.

✍ Scribed by Philip W. Dyer; John Fawcett; Gerald A. Griffith; Martin J. Hanton; Celine Olivier; Adam R. Patterson; Samuel Suhard

Publisher
John Wiley and Sons
Year
2005
Weight
16 KB
Volume
36
Category
Article
ISSN
0931-7597

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πŸ“œ SIMILAR VOLUMES

Regioselective electrophilic trifluorome
Regioselective electrophilic trifluoromethylation of substituted anilines and derivatives in superacid
✍ SΓ©bastien Debarge; Bruno Violeau; Nohair Bendaoud; Marie-Paule Jouannetaud; Jean πŸ“‚ Article πŸ“… 2003 πŸ› Elsevier Science 🌐 French βš– 223 KB

In a one pot procedure, treatment of chloro or methyl substituted acetanilides in HF/SbF 5 /CCl 4 followed by addition of HF/pyridine yields trifluoromethyl derivatives with high regioselectivity.