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Steric Influence on the Reactivity of the ( o -Carboranedithiolato)iridium(III) Complex [Ir( η 5 -C 5 Me 5 )( η 2 -S 2 C 2 B 10 H 10 )]: New Types of Addition Reactions Involving Cyclometalation or Isomerization †

✍ Scribed by Bae, Jin-Young; Lee, Young-Joo; Kim, Sung-Joon; Ko, Jaejung; Cho, Sungil; Kang, Sang Ook


Book ID
126054067
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
129 KB
Volume
19
Category
Article
ISSN
0276-7333

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✍ Paul-Michael Pellny; Vladimir V. Burlakov; Wolfgang Baumann; Anke Spannenberg; U 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 German ⚖ 213 KB 👁 1 views

The reactions of the bis(trimethylsilyl)acetylene permethylmetallocene complexes Cp 2 M(g 2 -Me 3 SiC 2 SiMe 3 ) (M = Ti (1), M = Zr (2)) with H 2 O and CO 2 were studied and compared to those of the corresponding metallocene complexes Cp 2 M(L)(g 2 -Me 3 SiC 2 SiMe 3 ) (M = Ti (3), L = ± ; M = Zr,