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Steric hindrance in the transfer of singlet electronic energy

โœ Scribed by Janda, Kenneth; Wettack, F. Sheldon


Book ID
127207187
Publisher
American Chemical Society
Year
1972
Tongue
English
Weight
305 KB
Volume
94
Category
Article
ISSN
0002-7863

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A search for steric effects on the rate
โœ Ahmad Yekta; Nicholas J. Turro ๐Ÿ“‚ Article ๐Ÿ“… 1972 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 357 KB

A study of eschange sir&t-singlet energy transfer was made between a series of stcrically hindered ketones end a-diketones in fluid cyclohesane. The comparison of the measured rate constants of energy transfer shows them to be nearly diffusion controlled and insensitive to stcric hindrance. This is