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Steric effects in singlet and triplet electronic energy transfer to azo compounds

โœ Scribed by Wamser, Carl C.; Medary, Richard T.; Kochevar, Irene E.; Turro, Nicholas J.; Chang, Peter L.

Book ID
126423266
Publisher
American Chemical Society
Year
1975
Tongue
English
Weight
804 KB
Volume
97
Category
Article
ISSN
0002-7863

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A study of eschange sir&t-singlet energy transfer was made between a series of stcrically hindered ketones end a-diketones in fluid cyclohesane. The comparison of the measured rate constants of energy transfer shows them to be nearly diffusion controlled and insensitive to stcric hindrance. This is