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Steric hindrance in the diene condensation of 1-tert-butylbutadiene

โœ Scribed by V. F. Kucherov; S. Ya. Metlyaeva; B. A. Rudenko


Book ID
112422848
Publisher
Springer
Year
1972
Tongue
English
Weight
76 KB
Volume
21
Category
Article
ISSN
1573-9171

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Diene condensation of 1-tert-butylbutadi
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Steric hindrance was observed during the oxidation of 2,4,6-tri-tert-butylphenylphosphole to the P oxide and in the dimerization of this latter species to the corresponding phosphanorbornene derivative. Single-crystal X-ray analysis of the dimer revealed considerable steric crowding around the P ato