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Steric effect on fluorescence quenching of 1,1'-binaphthyl by chiral amines

โœ Scribed by Irie, Masahiro; Yorozu, Takehiko; Hayashi, Koichiro

Book ID
125980549
Publisher
American Chemical Society
Year
1978
Tongue
English
Weight
279 KB
Volume
100
Category
Article
ISSN
0002-7863

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Enantiotopic interactions in the fluores
Enantiotopic interactions in the fluorescence quenching of camphor by chiral amines
โœ Marye Anne Fox; Nancy J. Singletary ๐Ÿ“‚ Article ๐Ÿ“… 1979 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 252 KB

A study of the quenching of fluorescence of (+)-and (-) camphor in hexane by a series of chiral primary, secondary, and tertiary amines shows only very small differences in quenching rate constants for the two enantiomers. The collision complex which precedes quenching (probably charge transfer) is