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Determination of the Enantiomeric Composition of Chiral Amines Based on the Quenching of the Fluorescence of a Chiral Calixarene

✍ Scribed by Grady, Teresa; Harris, Stephen J.; Smyth, Malcolm R.; Diamond, Dermot; Hailey, Perry

Book ID
127095476
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
265 KB
Volume
68
Category
Article
ISSN
0003-2700

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πŸ“œ SIMILAR VOLUMES

Enantiotopic interactions in the fluores
Enantiotopic interactions in the fluorescence quenching of camphor by chiral amines
✍ Marye Anne Fox; Nancy J. Singletary πŸ“‚ Article πŸ“… 1979 πŸ› Elsevier Science 🌐 French βš– 252 KB

A study of the quenching of fluorescence of (+)-and (-) camphor in hexane by a series of chiral primary, secondary, and tertiary amines shows only very small differences in quenching rate constants for the two enantiomers. The collision complex which precedes quenching (probably charge transfer) is