𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Steric and Polar Effects of the Cyclic Nitroxyl Fragment on the C−ON Bond Homolysis Rate Constant

✍ Scribed by Fischer, Hanns; Kramer, Andreas; Marque, Sylvain R. A.; Nesvadba, Peter

Book ID
127250038
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
249 KB
Volume
38
Category
Article
ISSN
0024-9297

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Chemically Triggered C–ON Bond Homolysis
Chemically Triggered C–ON Bond Homolysis in Alkoxyamines. Part 2: DFT Investigation and Application of the pH Effect on NMP
✍ Elena Bagryanskaya; Paul Brémond; Mariya Edeleva; Sylvain R. A. Marque; Dmitriy 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 627 KB

## Abstract In recent work, a 15‐fold increase in the C–ON bond homolysis rate constant __k__~d~ of 4‐pyridylethyl‐SG1‐based alkoxyamine was observed upon protonation of the pyridyl moiety in organic solvent. In this report, the pH dependence of __k__~d~ (p__K__~a~ = 4.7) is investigated in D~2~O/C