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Stereospecificity of the3JCHspin-spin coupling constants in bicyclic cis-diaziridines. Stereochemistry of 2,4,6-trialkyl-1,3,5-triazabicyclo[3.1.0]-hexanes

โœ Scribed by S. N. Denisenko; G. V. Shustov; I. I. Chervin; R. G. Kostyanovskii


Book ID
112356019
Publisher
Springer US
Year
1985
Tongue
English
Weight
447 KB
Volume
21
Category
Article
ISSN
0009-3122

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ChemInform Abstract: Stereospecific Synt
โœ S. N. DENISENKO; P. RADEMACHER; R. G. KOSTYANOVSKY ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 33 KB ๐Ÿ‘ 1 views

## Stereospecific Synthesis of Bicyclic Diaziridines: 4a-Chloro-; 4e,6a-and 4a,6e-Dichloro-5-methoxycarbonyl-1,6diazabicyclo[3.1.0]hexanes. -Amination of 3-chloro-1-pyrroline (I) with H 2 N-O-SO 3 H occurs predominantly from the anti side with respect to chlorine to afford diaziridine (II). Chlor