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Stereospecificity observed in base-catalyzed electrochemical oxidation

✍ Scribed by Mutsuo Okamura; Takeshi Kashiwagi; Yuji Mikata; Tetsushi Maruyama; Atsuyoshi Ohno

Book ID
103408464
Publisher
Elsevier Science
Year
1991
Tongue
French
Weight
176 KB
Volume
32
Category
Article
ISSN
0040-4039

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Base-catalyzed oxidation: Kinetics and mechanism of hexacyanoferrate (III) oxidation of methyl cellulose polysaccharide in alkaline solutions
✍ R.M. Hassan; S.M. Ibrahim; I.A. Zaafarany; A. Fawzy; H.D. Takagi πŸ“‚ Article πŸ“… 2011 πŸ› Elsevier Science 🌐 English βš– 407 KB

The kinetics of oxidation of methyl cellulose polysaccharide as a natural polymer by alkaline potassium ferricyanide at a constant ionic strength of 1.0 mol dm -3 have been studied, spectrophotometrically. The experimental results showed complex kinetics where the pseudo first-order plots were found