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Stereospecificity in the proton magnetic relaxation rate of enantiotopic methyls and the methyl rotation barrier

✍ Scribed by Yu. Yu. Samitov; R. Kh. Sadykov

Book ID
112361482
Publisher
Springer
Year
1987
Tongue
English
Weight
641 KB
Volume
22
Category
Article
ISSN
0040-5760

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✍ Dominique Lafleur; Yining Huang; Denis F.R. Gilson; Ian S. Butler πŸ“‚ Article πŸ“… 1994 πŸ› Elsevier Science 🌐 English βš– 139 KB

Proton spin-lattice relaxation times and \({ }^{13} \mathrm{C}\) chemical shift anisotropy measurements have been made on the complexes pentacarbonyl(methyl)manganese(I) and -rhenium(I), \(\mathrm{CH}_{3} M(\mathrm{CO})_{5}\), \(M=\) \(\mathrm{Mn}, \mathrm{Re})\). The barrier to rotation of the meth