Rotational tunneling and proton nuclear magnetic resonance of the methyl group in the CH3SiCl3 crystal
β Scribed by Sadamu Takeda; Hideaki Chihara
- Publisher
- Elsevier Science
- Year
- 1984
- Weight
- 800 KB
- Volume
- 56
- Category
- Article
- ISSN
- 0022-2364
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π SIMILAR VOLUMES
Rcccivcd 14 Scptcmbcr 1970 Anisotropies 01 the 13C shielding constant @UC) for CIinI and Cll+!X arc obtained from 'k SMi1 studies of these molcculcs in the ncmatic solvents. The results arc compnrcd with the Lhcorctkal vnlues obtained by the molccuklr orhitnl cnlculxtions using thz current theory. T
## Abstract Accurate parameters for the two title compounds have been obtained by the aid of a spectral subtraction technique in conjunction with analysis by LAOCN3. It is observed that __J__~1eq, 6eq~ and __J__~1ax, 2ax~ are abnormally large and small, respectively, and the significance of these a