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Stereospecific Synthesis of (−)-β-Turmerone and (−)-Bisacurol

✍ Scribed by Wolfgang Kreiser; Ferdinand Körner


Publisher
John Wiley and Sons
Year
1999
Tongue
German
Weight
242 KB
Volume
82
Category
Article
ISSN
0018-019X

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Stereospecific Synthesis of (+)-β-Sesqui
✍ Wolfgang Kreiser; Ferdinand Körner 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 German ⚖ 91 KB

The structure and absolute configuration of (À)-b-Sesquiphellandrene ((À)-1a) is shown to be (6S)-2methyl-6-[(1'R)-4-methylidenecyclohex-2-enyl]hept-2-ene by stereospecific synthesis of its enantiomer (()-1a) and of a further (6S,1'S)-diastereoisomer (()-1b). Characteristic spectroscopic differences