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ChemInform Abstract: Stereospecific Synthesis of (-)-β-Turmerone and (-)-Bisacurol

✍ Scribed by Wolfgang Kreiser; Ferdinand Koerner

Publisher
John Wiley and Sons
Year
2010
Weight
28 KB
Volume
31
Category
Article
ISSN
0931-7597

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The structure and absolute configuration of (À)-b-Sesquiphellandrene ((À)-1a) is shown to be (6S)-2methyl-6-[(1'R)-4-methylidenecyclohex-2-enyl]hept-2-ene by stereospecific synthesis of its enantiomer (()-1a) and of a further (6S,1'S)-diastereoisomer (()-1b). Characteristic spectroscopic differences