𝔖 Bobbio Scriptorium
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Stereospecific synthesis of methyl 2,6-diacetamido-2,3,6-trideoxy-α-D-ribohexofuranoside and hexopyranoside, derivatives of tobrosamine

✍ Scribed by Jean-Claude Florent; Claude Monneret


Book ID
103397761
Publisher
Elsevier Science
Year
1981
Tongue
French
Weight
305 KB
Volume
37
Category
Article
ISSN
0040-4020

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The title glycosides were synthesised from D-glUCOSe, via the common intermediate methyl 2-acetamido-4-O-benzoyld-bromo-2,3,6-trideoxy-a-D-ribohexopyranoside . \*To whom enquiries should be addressed. \*\*The overall efficiency of this procedure can be improved by using a phase-transfer process' in

Synthesis and 13C-N.m.r. spectra of meth
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ABSTRACf Previously unknown methyl 2,3-diacetamido-2,3-dideoxy-a-D-hexopyranosides having the gulo, allo, galacto, ido, and altro configurations, as well as 2,3-diacetamido-2,3-dideoxy-D-galactose, have been synthesised. 13C-N.m.r. data for all eight methyl 2,3-diacetamido-2,3-dideoxy-cu-D-hexopyran