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Stereospecific synthesis of EET metabolites via Suzuki–Miyaura coupling

✍ Scribed by J.R Falck; P.Srinagesh Kumar; Y.Krishna Reddy; Gang Zou; Jorge H Capdevila

Book ID
104231584
Publisher
Elsevier Science
Year
2001
Tongue
French
Weight
95 KB
Volume
42
Category
Article
ISSN
0040-4039

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A simple and efficient total synthesis of ellipticine was developed via the Suzuki-Miyaura coupling of sterically sensitive 2-hydroxybenzeneboronic acid with a multifunctional aryl halide using Pd(OAc) 2 as a catalyst and Cu(OAc) 2 ÁH 2 O as an additive in DMSO/H 2 O as a key step followed by double