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Stereospecific Synthesis of D-Hydroxynitriles and Optically Active Ethanolamines

✍ Scribed by Dr. W. Becker; H. Freund; Prof. Dr. E. Pfeil

Publisher
John Wiley and Sons
Year
1965
Tongue
English
Weight
136 KB
Volume
4
Category
Article
ISSN
0044-8249

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## Abstract The reduction of dimenthyl ketophosphonates with sodium borohydride involves asymmetric induction at the α‐carbon atom, resulting in a small excess of the (R)‐enantiomer of the α‐hydroxyphosphonate formed. A higher ee purity was achieved if the reduction of chiral dimenthyl ketophosphon