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Stereospecific synthesis of cis–trans-dicyclohexano-18-crown-6 and K+ complexation by the five dicyclohexano-18-crown-6 isomers

✍ Scribed by Kazuhiro Yamato; Fernando A Fernandez; Howard F Vogel; Richard A Bartsch; Mark L Dietz

Publisher
Elsevier Science
Year
2002
Tongue
French
Weight
180 KB
Volume
43
Category
Article
ISSN
0040-4039

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✦ Synopsis

Stereospecific syntheses of the cis-trans-isomer of dicyclohexano-18-crown-6 allows the K + complexation behavior of all five dicyclohexano-18-crown-6 isomers to be compared.

📜 SIMILAR VOLUMES

Synthesis of chiral trans-anti-trans-iso
Synthesis of chiral trans-anti-trans-isomers of dicyclohexano-18-crown-6 via an enzymatic reaction and the solid-state structure of one enantiomer
✍ Kazuhiro Yamato; Richard A. Bartsch; Grant A. Broker; Robin D. Rogers; Mark L. D 📂 Article 📅 2002 🏛 Elsevier Science 🌐 French ⚖ 232 KB

Chiral trans-anti-trans-dicyclohexano-18-crown-6 isomers are synthesized via a lipase-catalyzed reaction. The solidstate structure of the (S)-enantiomer is determined and compared with those reported for 18-crown-6 and trans-syn-trans-dicyclohexano-18-crown-6.

ChemInform Abstract: Synthesis, Structur
ChemInform Abstract: Synthesis, Structure, and Ion Selective Complexation of trans and cis Isomers of Photochromic Dithia-18-crown-6 Ethers.
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