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Stereospecific Synthesis of 3,3-Disubstituted Acrylonitriles by Heck Reaction.

✍ Scribed by Judit Masllorens; Marcial Moreno-Manas; Anna Pla-Quintana; Roser Pleixats; Anna Roglans

Publisher
John Wiley and Sons
Year
2003
Weight
113 KB
Volume
34
Category
Article
ISSN
0931-7597

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Synthesis of Sultams by Intramolecular H
Synthesis of Sultams by Intramolecular Heck Reaction
✍ Sandra Merten; Roland FrΓΆhlich; Olga Kataeva; Peter Metz πŸ“‚ Article πŸ“… 2005 πŸ› John Wiley and Sons 🌐 English βš– 170 KB πŸ‘ 1 views

## Abstract A novel access to α‐methylene‐γ‐sultams __via__ the intramolecular Heck reaction of α‐bromovinylsulfonamides derived from allylic amines is reported. These heterocycles are potent Michael acceptors towards sulfur nucleophiles.