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Stereospecific Syntheses of D-Ossamine and D-Tolyposamine

โœ Scribed by Malik, Abdul ;Afza, Nighat ;Voelter, Wolfgang

Publisher
John Wiley and Sons
Year
1984
Tongue
English
Weight
303 KB
Volume
1984
Category
Article
ISSN
0947-3440

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โœฆ Synopsis

Abstract

2,3,4,6โ€Tetradesoxyโ€4โ€(dimethylamino)โ€Dโ€threoโ€hexose (Dโ€ossamine, 7), the amino sugar fragment from the fungal metabolite ossamycin, and 4โ€aminoโ€2,3,4,6โ€tetradeoxyโ€Dโ€erythroโ€hexose (Dโ€tolyposamine, 12), the enantiomeric constituent of the antibiotic tolypomycin, have been synthesized from Dโ€glucose via hexโ€2โ€enopyranosides.

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