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Stereospecific Syntheses of 7β-AND 7α -Hydroxycholesterols

✍ Scribed by Kumar, Vijay; Amann, Alain; Ourisson, Guy; Luu, Bang


Book ID
118215128
Publisher
Taylor and Francis Group
Year
1987
Tongue
English
Weight
217 KB
Volume
17
Category
Article
ISSN
0039-7911

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Stereospecific total syntheses of 7α- an
✍ Peter A. Jacobi; Roger F. Frechette 📂 Article 📅 1987 🏛 Elsevier Science 🌐 French ⚖ 246 KB

## Summan: The title compounds have been prepared in a highly eficientfashion by a synthetic route involving an intramolecular Diels-Alder reaction of an acetylenic thiazole followed by reductive modification of the resulting fused-ring thiophene. 13. Models indicate that the difference in selecti