Stereospecific Rearrangements during the Synthesis of Pyrrolidines and Related Heterocycles from Cyclizations of Amino Alcohols with Vinyl Sulfones
โ Scribed by Back, Thomas G.; Parvez, Masood; Zhai, Huimin
- Book ID
- 121492342
- Publisher
- American Chemical Society
- Year
- 2003
- Tongue
- English
- Weight
- 107 KB
- Volume
- 68
- Category
- Article
- ISSN
- 0022-3263
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๐ SIMILAR VOLUMES
The titled amino alcohols are obtained by treatment of chiral amino acids with triallylborane. Electrophylic iodocyclization of the alcohols leads to pyrrolidine derivatives. @ 1997 Elsevier Science Ltd. Optically active 2-amino alcohols are widely used in organic synthesis as chiral inductors,l-3
Synthesis of Enantiopure 1,4-Dioxanes, Morpholines, and Piperazines from the Reaction of Chiral 1,2-Diols, Amino Alcohols, and Diamines with Vinyl Selenones. -The reaction of enantiopure diols, amino alcohols, or diamines with vinyl selenones in the presence of NaH represents a novel route to the ti