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Stereospecific polymerizations of cycloalkenes induced by a metal-carbene

✍ Scribed by Thomas J. Katz; Steven J. Lee; Nancy Acton


Book ID
103404011
Publisher
Elsevier Science
Year
1976
Tongue
French
Weight
250 KB
Volume
17
Category
Article
ISSN
0040-4039

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Water-soluble manganese(II1) as well as iron(II1) porphyrinates are introduced as light-sensitive precursor compounds for the photocatalytic activation of dioxygen in aqueous solutions. It is shown that in the presence of a-pinene (4) and the further cycloalkenes 11 -13 photocatalytic oxygenation re