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Stereospecific palladium/copper cocatalyzed cross-coupling of .alpha.-alkoxy- and .alpha.-aminostannanes with acyl chlorides

โœ Scribed by Ye, Jianhua; Bhatt, Rama K.; Falck, J. R.

Book ID
126241868
Publisher
American Chemical Society
Year
1994
Tongue
English
Weight
581 KB
Volume
116
Category
Article
ISSN
0002-7863

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Palladium/Copper (I) halide-cocatalyzed stereospecific coupling of 1-fluorovinylstannanes with aryl iodides and acyl chlorides
โœ Chen Chen; Keith Wilcoxen; Kyung-il Kim; James R. McCarthy ๐Ÿ“‚ Article ๐Ÿ“… 1997 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 221 KB

Cross-coupling of 1-fluorovinylstannanes with aryl iodides or acyl chlorides, cocatalyzed by palladium and copper (I) iodide proceeded under mild conditions to give substituted fluoro oleflns and ot-fluoro-ct,~-unsaturated ketones, respectively, in good yields with retention of configuration.