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Stereospecific intramolecular insertion of the cyclopropylidenes produced in the reaction of cis- and trans-3-tert-butyl-7,7-dibromobicyclo[4.1.0]heptane with methyllithium

✍ Scribed by Moore, William Robert; King, Barbara Jean

Book ID: 125899755
Publisher: American Chemical Society
Year: 1971
Tongue: English
Weight: 907 KB
Volume: 36
Category: Article
ISSN: 0022-3263
DOI: 10.1021/jo00813a007

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## Abstract Four bicyclic dioxetanes bearing a phenolic substituent, 3‐__tert__‐butyldimethylsiloxy‐4‐chlorophenyl (**3a**), 5‐__tert__‐butyldimethylsiloxy‐4‐chloro‐2‐ethylphenyl (**3b**), 5‐__tert__‐butyldimethylsiloxy‐2‐ethylphenyl (**3c**), and 3‐__tert__‐butyldimethylsiloxy‐4‐ethylphenyl (**3d*