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Stereospecific, Enantiospecific Total Synthesis of the Sarpagine Indole Alkaloids ( E )16-Epiaffinisine, ( E )16-Epinormacusine B, and Dehydro-16-epiaffinisine

✍ Scribed by Yu, Jianming; Liao, Xuebin; Cook, James M.

Book ID: 125945110
Publisher: American Chemical Society
Year: 2002
Tongue: English
Weight: 89 KB
Volume: 4
Category: Article
ISSN: 1523-7060
DOI: 10.1021/ol020209c

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Stereospecific, Enantiospecific Total Sy

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The first enantiospecific total synthesis of the 3-oxygenated sarpagine indole alkaloids affinine (1) and 16-epiaffinine (2) as well as the synthesis of vobasinediol (3) and 16-epivobasinediol (4) was accomplished from D-(+)-tryptophan methyl ester.

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