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Stereospecific addition of alkylcopper reagents to .alpha.,.beta.-acetylenic acids. The nature of the vinylic enolate

โœ Scribed by Klein, Joseph; Turkel, R. M.


Book ID
126993733
Publisher
American Chemical Society
Year
1969
Tongue
English
Weight
225 KB
Volume
91
Category
Article
ISSN
0002-7863

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The addition of alkylcopper complexes to acetylenes (equation l), originally developed by Normantl and later investigated by Westmijze, 2 is a very useful approach to the synthesis of olefins. More recently we3 and others4 have modified this reaction through use of