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Determination of the configurations of trisubstituted olefins obtained from addition of alkylcopper complexes to acetylenes. Use of a lanthanide nmr shift reagent

✍ Scribed by Paul R. McGuirk; Anthony Marfat; Paul Helquist


Publisher
Elsevier Science
Year
1978
Tongue
French
Weight
266 KB
Volume
19
Category
Article
ISSN
0040-4039

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✦ Synopsis


The addition of alkylcopper complexes to acetylenes (equation l), originally developed by Normantl and later investigated by Westmijze, 2 is a very useful approach to the synthesis of olefins. More recently we3 and others4 have modified this reaction through use of