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Stereoselectivity in the photochemical cycloelimination of some polycyclic cyclobutanones

โœ Scribed by Miller, R. D.; Abraitys, V. Y.

Book ID
127170234
Publisher
American Chemical Society
Year
1972
Tongue
English
Weight
428 KB
Volume
94
Category
Article
ISSN
0002-7863

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โœ R.D. Miller ๐Ÿ“‚ Article ๐Ÿ“… 1977 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 249 KB

Over the years there has been considerable interest in the nature of the intermediate produced via solvolysis of cyclobutyl systems. Current feeling is that this process is best described by a concerted, symmetry allowed disrotatory ring opening proceeding from the side opposite to the leaving group